MSE 455/555

 Environmental Degradation

Term Offered: Spring
Text(s):

Principles and Prevention of Corrosion, 2nd Ed., D. A. Jones, Prentice Hall, Atlas of Electrochemical Equilibria in Aqueous Solutions, M. Pourbaix, NACE (1974)
Metals Handbook, Vol. 13: Corrosion, 9th Ed., ASM International (1987)

Instructor(s): Professor Wayne Worrell, Room 300 LRSM, worrell@seas.upenn.edu, 898-8592
Prerequisite(s): MSE 220
Grading:  
Course Home Page URL:  
Course Description: This course is designed to provide an understanding of the principles and methods used to minimize and prevent corrosion. Metals and alloys are emphasized because these are the materials in which corrosion is the most prevalent. Aqueous environments are also emphasized because these are common corrosion conditions.

In the first half of the course, the impact and electrochemical nature of corrosion are described, and then the corrosion fundamentals (electrochemical reactions, phase (pourbaix) diagrams, aqueous corrosion kinetics, passivity, and high-temperature oxidation) are emphasized. The forms of corrosion (galvanic, pitting and crevice, environmentally induced cracking) and corrosion prevention (protection methods) are accentuated in the second half. Corrosion in the human body (for example, surgical implants and prosthetic devices) and in other selective environments (concrete, seawater, and water solutions containing dissolved salts, sulfur, and bacteria) are also described in the second half.

Course Outline: 1. Thermodynamic Analysis and Applications of Pourbaix Diagrams
2. Corrosion Kinetics and Mixed Potential Theory
3. Passive Films, Anodic Polarization and Protection
4. High Temperature Oxidation of Metals and Alloys
5. Galvanic Corrosion
6. Pitting and Crevice Corrosion
7. Metallurgical Effects and Environmental Induced Cracking
8. Metallic Implants/Prosthetic Devices and Other Biomaterials
9. Other Common Corrosive Environments
10. Common Corrosion Protection Methods
11. Oral Presentations of Individual Corrosion Case Studies
 


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