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In methane the bonding network of the carbon atoms is terminated by the H atoms. Because the H atoms can only form one covalent bond, which is confined within the molecule, there is no possibility for extended covalent bonding between different molecules. The inter-molecular bonds must therefore rely on weaker dispersion forces for their cohesive forces.
In diamond, which can be constructed by replacing the H atoms in methane
by other C atoms, the bonding is not terminated and the s
sp3 bonds between the C atoms are extended throughout the solid.
These are strong bonds, as a result diamond has a very high melting (>3550°C)
and boiling (4827°C) point. (for a more detailed description of the
bonding go to Conduction properties)
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The crystal strucutre of diamond is comprised of tetrahedrally
coordinated C atoms. The unit cell is fcc, with 2 carbon atoms per
lattice point, and 8 atoms per cell.
The diamond structure is also adopted by several well known semi-conductors
such as Si, Ge (and also gray Sn).